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Types of
Polymers
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1. Thermoplastics
(can be melted with the application of heat).
- Crystalline
crystallize when cooled
- Amorphous
no crystallization when cooled
- Semicrystallin
polymers which contain both crystalline and amorphous segments
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2.
Thermosets (degrade rather than melt with the application of heat) |
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3.
Elastomers (cross-linked) |
Plastics
are rigid long-chain polymers which are not usually connected or cross-linked.
Plastics can either be thermoplastic-meaning they can be heated and
cooled without changing propertiesor - thermoset, where an increase
in temperature changes the chemical structure and properties. As a class,
plastics have low elongation and high elongation set.
Elastomers
are flexible long-chain polymers which are capable of cross-linking.
Cross-linking chemically bonds polymer chains which can prevent reversion
to a non-cross-linked polymer at elevated temperatures. The cross-link
is the key to the elastic, or rubbery, properties of these materials.
The elasticity provides resiliency in sealing applications.
Thermoplastic
elastomers (TPEs) often combine the properties of elastomers with the
ease of processability of thermoplastics. They are the result of a physical
combination of soft, elastic polymer segments and hard, crystalline
segments which are capable of cross-linking. Thermoplastic elastomers
are generally classified by their structure rather than their chemical
makeup.
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Topic O-ring
and Seal Materials
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